Supporting information for “Self-assembly of multicomponent structures in and out of equilibrium’

نویسندگان

  • Stephen Whitelam
  • Rebecca Schulman
  • Lester Hedges
چکیده

The analytic theory developed in the main text is a dynamical mean-field one, which focuses on the likelihood φ ≡ [(ηi + 1)/2] that a given fiber bond is a bulk one. Here ηi ≡ SiSi+1, is a ‘defect variable’: ηi = 1 describes a bulk (same-color) bond, and ηi = −1 is a defect (unlike-color) one. We expect a mean-field theory of this nature to be most accurate when red and blue blocks are added to the fiber with equal likelihood, because, in this limit, the Ising model representation of fiber energetics can be written in the noninteracting (space-independent) form H = −Ji ηi.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Self-assembly of multicomponent structures in and out of equilibrium.

Theories of phase change and self-assembly often invoke the idea of a "quasiequilibrium," a regime in which the nonequilibrium association of building blocks results nonetheless in a structure whose properties are determined solely by an underlying free energy landscape. Here we study a prototypical example of multicomponent self-assembly, a one-dimensional fiber grown from red and blue blocks....

متن کامل

Electrocatalytic multicomponent assembling of aldehydes, dimedone and 1-naphthylamine for synthesis of novel tetrahydrobenzo[c]acridin-8(7H)-one derivatives

An efficient and convenient synthesis of novel tetrahydrobenzo[c]acridin-8(7H)-one derivatives is described using the electrogenerated anion of acetonitriles as the base in the presence of tetrabutylammonium fluoride as an effective supporting electrolyte in a one-pot, three-component condensation of aromatic aldehyde, dimedone and 1-naphthyl amine. The reaction is carried out in an undivided c...

متن کامل

Making Optimal Decisions of Assembly Products in Supply Chain

The strategic pricing decisions of assembly products in assembly products supply chain are studied in this paper. Firstly, a two-stage assembly products supply chain model is developed. By building Nash game model, the Nash equilibrium solution of pricing strategy of supplier and assemblers is obtained. Next, a union decision model is built to analyze the optimal combination pricing strategy of...

متن کامل

Quantum Chemical Investigations on C14C10-Branched-Chain Glucoside Isomers Towards Understanding Self-Assembly

Density Functional Theory (DFT) calculations have been carried out using a Polarizable Continuum Model (PCM) in an attempt to investigate the electro-molecular properties of branched-chain glucoside (C14C10-D-glucoside) isomers. The results showed that αconfiguration of pyranoside form is thermodynamically the most stable, while the solution should contain much more β...

متن کامل

Aminothiophenol Furfural Self-assembled Gold Electrode Sensor for Determination of Dopamine in Pharmaceutical Formulations

A new Schiff base 2-aminothiophenol furfural self assembled monolayer (SAM) has been fabricated on a bare gold electrode as a novel sensor for determination of dopamine. Electrochemical impedance spectroscopywas utilized to investigate the properties of the Au 2-aminothiophenol furfural self assembled monolayermodified electrode (Au ATF SAM-ME) using the [Fe(CN)6]3-/4- redox couple. The electro...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2012